Why do you think it has some build-up? Any real symptoms, or just a bit of paranoia about former owners?
As Rene said, filling the tank with fresh water and adding Rid EX or Roebic is a good way to get a general clean-up of tank walls, sensors, etc. Let it soak 3+ days and then flush out well. Can't hurt and doesn't take much effort. Rid Ex is widely available, but Roebic is nearly so (Lowes, many hardware stores, etc) and Roebic makes tailored products for various purposes. Their K37 and K57 products do well on Rv systems, and they also have a product tailored for RVs.
http://www.roebic.com/rv-marine-black-water-treatment.shtml
I've used both RidEx and Roebic products with similar results.