Assuming it's a sunny day, a healthy 100 watt solar panel should put out about 20 - 21 volts and roughly 5 - 6 amps. When hooked to a controller, however, the controller's output may show something completely different, depending on the battery's State Of Charge and whether or not the RV is plugged into shore power.
For example, when NOT hooked up to shore power, the controller should indicate an output of about 13 - 14 volts and roughly 5 - 6 amps if the battery is discharged, because the controller is trying to charge the battery. If the battery is fully charged, the controller will sense this and reduce its output correspondingly. The exact amount depends on programming and SOC.
It's not unusual for a panel's output to fluctuate significantly in breezy conditions when parked under a tree, or when clouds are passing by. In steady sunlight, however, a panel's output should remain relatively stable. If you're seeing wildly fluctuating voltages from the panel's output in steady sunlight, you may have a bad connection somewhere, or a bad panel. I have seen flexible panels exhibit similar symptoms when they're going bad.
Kev