It is possible that a vent might be plugged, or installed too far down into the tank. Check it out first with a flashlight. You many need to insert a long, sturdy stick or rod to knock a blockage back into the tank. If one is there, let it soak well in hot water in the tank for a while before opening the dump valve. You don't want it to plug the dump valve or pipe. That can get REALLY messy and frustrating.
The latter is the case with my Fox's tank, so I don't get full use of the tank capacity without it starting to smell in hot weather. Raising the vent pipe can be a MAJOR undertaking, so I've learned to live with it and dump a little sooner. Try to precharge your black tank with at least 10 gallons of water before use. The more water you have, the more smell is diluted.
There may be some kind of chemical residue left in the tank from previous owners. Rinse, for hours if necessary, using a wand that goes down into the tank and can spray the corners really well.
NEVER, NEVER use anything with chlorine in your black tank! It mixes with urine and makes a DEADLY gas!