Refer to kcmusa's answer - it depends on the battery type (6v vs 12v) I've attached to diagrams, one for a pair of 6v batteries and one for 12v. For the 12v pair, you can connect the charger to the positive and negative of either battery and charge both. For the 6V pair, you must attach to the + terminal labeled 12v+ and the - terminal labeled Ground in the photo. The charger must be set to 12v, not 6v.I assume either one can be charged to charge them both?