Battery efficiency differences aside, the range of a 6 battery pack vs an 8 battery pack will be about 25% less. It amounts to pounds of lead, an 8V battery weighs about the same as a 6V one. Take two away and it's that much less power available.
8V batteries will be a little more expensive per pound because they're not made in the volumes of 6V. Depending on your range requirement the cost savings of buying two less batteries is greater than the unit cost of the 8V so for some applications it's cost effective. In terms of delivered power (Wh) they're about the same as a 6V but if you're using two fewer batteries, you'll get that much less delivered power as a pack. The plus is you've reduced the weight by ~120lbs, or gained the space of two batteries. You still have the same number of cells to service for a given voltage pack. So it's not a question of whether 8V is "better", just depends on what your goal is. You could come up with a combination of 12V to accomplish a particular volume/weight/cost goal too.
Mark B.
Albuquerque, NM