Gary and Lou,
You're both right - to a degree. Almost all matter can exist in one of three 'phases' - solid, liquid, and gaseous(vapor). The point at which a solid becomes a liquid is the melting point; the point where a liquid becomes a gas is called the boiling point. It all depends on a combination of temperature and pressure. Interestingly, some substances can exist as a solid, liquid, and vapor all at the same temperature/pressure. This is called the triple point, but is not pertinent to our discussion of propane. If you evacuate a container and then pour in some propane (C3H8), some of the liquid propane will change phases and go from liquid to vapor until equilibrium is reached and it is at this temperature/pressure combination that the process stops. In truth it still continues, but an equal amount of gas returns to the liquid phase, so the net change is zero. At equilibrium you can measure the pressure of the gas in the cylinder, and that is what's called the vapor pressure. At equilibrium, if no additional heat is added or lost and the pressure remains constant (as it would in a closed container like a propane tank) the respective volumes of liquid and gas will remain constant. As you draw the gas off (like turning on a stove burner), the pressure inside the container will drop and more of the liquid will change into the gas phase and the vapor pressure will remain constant. This is true until there is no more liquid in the tank to change into vapor. At that point, the pressure of the gas being drawn off will continue to drop until it finally equals atmospheric pressure; then flow will stop. It is for these reasons that a pressure gauge is useless for determining the amount of liquid propane remaining in a tank. As Gary mentioned, temperature is one of the variables in determining vapor pressure. If your tank becomes hot, the pressure will increase and force some of the vapor back into the liquid phase. Too much heat, and there won't be much vapor left to convert back to liquid, and the pressure could reach dangerous levels. Conversly, if you were to travel to a place where the temperature is -108F and had a normal atmospheric pressure, no gas would flow at all because you would be below the boiling point of the propane (-107.1F). I don't think many of us have to worry about that! ;D There is another temperature/pressure combination referred to as the Critical Point. For propane it is 204F at 609lbs/sq. inch. It is at the critical point where no amount of additional heat or pressure will change the gas back into a liquid. Obviously, the safety pressure relief valves on our tanks are set well below that point.