I will probably start a feud ,something simular to "what is better, a Ford, Ram, or Chevy" .BUTTTT , I was getting tires put on our camper and ended up with some mindless banter with a very well seasoned tire changer that drove a major service truck from the tire outlet about air pressure changes in tires. I cautiously asked about the details of Nitrogen filled tires.
He actually explained in a fairly reasonable way about the lack of a large increase and then decrease in tire pressure with Nitrogen filled tires versus tires filled with air. The molecules , I think the make up of Nitrogen, IIRC is more dense and consumes a larger area in a confined area inside the tire versus straight air. I am not an expert in areas such as this, except in hot air of opinions and an expert in asking questions.
But he went on to say that he runs nitrogen in his riding lawn mowers, which he swears that deals with a more stable pressure over the seasonable and ambient temperature changes, reducing the constant issues of checking and filling the tires to uniform pressure to get even cuts in his acres of grass.